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(1S*,2R*,6R*,7R*,11S*)-6-hydroxy-2-methyl-1-(methoxycarbonyl)-8-methylene-3-oxo-11-(trimethylsiloxy)tricyclo<5.3.1.02,6>undecane

(1S,2R,6R,7R,11S*)-6-hydroxy-2-methyl-1-(methoxycarbonyl)-8-methylene-3-oxo-11-(trimethylsiloxy)tricyclo<5.3.1.02,6>undecane

CAS号：82891-03-0

英文名：(1S*,2R*,6R*,7R*,11S*)-6-hydroxy-2-methyl-1-(methoxycarbonyl)-8-methylene-3-oxo-11-(trimethylsiloxy)tricyclo<5.3.1.02,6>undecane

分子式

C18H28O5Si

熔点

147 - 148.5 °C (四氯化碳)

密度

分子量

352.497

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(1S*,2R*,6R*,7R*,11S*)-6-hydroxy-2-methyl-1-(methoxycarbonyl)-8-methylene-3-oxo-11-(trimethylsiloxy)tricyclo<5.3.1.02,6>undecane

英文名称

(1S*,2R*,6R*,7R*,11S*)-6-hydroxy-2-methyl-1-(methoxycarbonyl)-8-methylene-3-oxo-11-(trimethylsiloxy)tricyclo<5.3.1.02,6>undecane

中文别名

英文别名

(1S*,2R*,6R*,7R*,11S*)-6-hydroxy-2-methyl-1-(methoxycarbonyl)-8-methylene-3-oxo-11-(trimethylsiloxy)tricyclo[5.3.1.02,6]undecane、(8R,8aR,9S)-8a-Hydroxy-3a-methyl-7-methylene-3-oxo-9-trimethylsilanyloxy-octahydro-4,8-methano-azulene-4-carboxylic acid methyl ester

CAS号

82891-03-0

分子式

C18H28O5Si

分子量

352.497

精确质量

352.171

PSA

72.83

LOGP

2.446

物化性质

熔点

147 - 148.5 °C (四氯化碳)

合成路线

共找到21条合成路线 >

3-Chloro-2-(1-methyl-2,5-dioxo-cyclopentyl)-propionic acid methyl ester

3-Chloro-2-(1-methyl-2,5-dioxo-cyclopentyl)-propionic acid methyl ester

(1S*,2R*,6R*,7R*,11S*)-6-hydroxy-2-methyl-1-(methoxycarbonyl)-8-methylene-3-oxo-11-(trimethylsiloxy)tricyclo<5.3.1.02,6>undecane

(1S*,2R*,6R*,7R*,11S*)-6-hydroxy-2-methyl-1-(methoxycarbonyl)-8-methylene-3-oxo-11-(trimethylsiloxy)tricyclo<5.3.1.02,6>undecane

上游原料

共找到3个上游原料 >

2-methyl-2-<1-(methoxycarbonyl)ethen-1-yl>-1,3-cyclopentanedione

2-methyl-2-<1-(methoxycarbonyl)ethen-1-yl>-1,3-cyclopentanedione

Silane, trimethyl[[(1E)-3-methyl-1,3-butadienyl]oxy]-

Silane, trimethyl[[(1E)-3-methyl-1,3-butadienyl]oxy]-

3-Chloro-2-(1-methyl-2,5-dioxo-cyclopentyl)-propionic acid methyl ester

3-Chloro-2-(1-methyl-2,5-dioxo-cyclopentyl)-propionic acid methyl ester

下游产品

共找到21个下游商品 >

(1R*,2'R*,4R*,8R*)-8-methyl-3-oxabicyclo<3.3.0>octa-2,7-dione-1-spiro-1'-(4'-methyl-2'-(trimethylsiloxy)-3'-cyclohexene)

(1R*,2'R*,4R*,8R*)-8-methyl-3-oxabicyclo<3.3.0>octa-2,7-dione-1-spiro-1'-(4'-methyl-2'-(trimethylsiloxy)-3'-cyclohexene)

Propionic acid (1S,2R,7R,9R,11R)-2-hydroxymethyl-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-yl ester

Propionic acid (1S,2R,7R,9R,11R)-2-hydroxymethyl-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-yl ester

(1R,2S,7S,9S,11R)-2-Hydroxymethyl-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol

(1R,2S,7S,9S,11R)-2-Hydroxymethyl-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol

rac-(1R,2R,3a'R,6a'R)-5'-bromo-3a',4-dimethyl-2-((trimethylsilyl)oxy)-3a',5',6',6a'-tetrahydro-2'H,4'H-spiro[cyclohexane-1,3'-cyclopenta[b]furan]-3-ene-2',4'-dione

rac-(1R,2R,3a'R,6a'R)-5'-bromo-3a',4-dimethyl-2-((trimethylsilyl)oxy)-3a',5',6',6a'-tetrahydro-2'H,4'H-spiro[cyclohexane-1,3'-cyclopenta[b]furan]-3-ene-2',4'-dione

rac-(1aR,3aR,4S,5R,7R,8aS,8bS)-3a-(((tert-butyldimethylsilyl)oxy)methyl)-1a,4-dimethyl-9-methylenedecahydro-4,7-methanooxireno[2',3':5,6]benzo[1,2-b]oxepin-5-ol

rac-(1aR,3aR,4S,5R,7R,8aS,8bS)-3a-(((tert-butyldimethylsilyl)oxy)methyl)-1a,4-dimethyl-9-methylenedecahydro-4,7-methanooxireno[2',3':5,6]benzo[1,2-b]oxepin-5-ol

(1S,2R,7R,9R,11R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol

(1S,2R,7R,9R,11R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol

上游原料

2-methyl-2-<1-(methoxycarbonyl)ethen-1-yl>-1,3-cyclopentanedione 3-Chloro-2-(1-methyl-2,5-dioxo-cyclopentyl)-propionic acid methyl ester

下游产品

(1R*,2'R*,4R*,8R*)-8-methyl-3-oxabicyclo<3.3.0>octa-2,7-dione-1-spiro-1'-(4'-methyl-2'-(trimethylsiloxy)-3'-cyclohexene) Propionic acid (1S,2R,7R,9R,11R)-2-hydroxymethyl-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-yl ester (1R,2S,7S,9S,11R)-2-Hydroxymethyl-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol rac-(1R,2R,3a'R,6a'R)-5'-bromo-3a',4-dimethyl-2-((trimethylsilyl)oxy)-3a',5',6',6a'-tetrahydro-2'H,4'H-spiro[cyclohexane-1,3'-cyclopenta[b]furan]-3-ene-2',4'-dione rac-(1aR,3aR,4S,5R,7R,8aS,8bS)-3a-(((tert-butyldimethylsilyl)oxy)methyl)-1a,4-dimethyl-9-methylenedecahydro-4,7-methanooxireno[2',3':5,6]benzo[1,2-b]oxepin-5-ol (1S,2R,7R,9R,11R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol Propionic acid (2R,7R,11R)-2-(tert-butyl-dimethyl-silanyloxymethyl)-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-yl ester rac-(3R,3aR,5S,6aS,10aR)-3a,8-dimethyl-4-methylene-3,3a,4,5,6a,9-hexahydro-1H,10H-3,5-methanofuro[3,4-d]chromen-1-one 15-(tert-butyldimethylsiloxy)-12,13-epoxytrichothecane-9-ene (1R*,2'R*,4R*,8R*)-8-methyl-3-oxabicyclo<3.3.0>octa-2,7-dione-1-spiro-1'-(2'-hydroxy-4'-methyl-3'-cyclohexene) (1R,2S,7R,9S,11R)-2-Hydroxymethyl-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol 15-(tert-butyldimethylsiloxy)-4α-hydroxytrichothecane-9,12-diene 5,14-Dimethyl-2,10-dioxa-9,13-dioxotetracyclo[6.4.2.03,8.011,14]tetradecan-4-ene 15-(tert-butyldimethylsiloxy)-4α-tosyloxytrichothecane-9,12-diene (1S*,4S*,7R*,8R*,12S*,13S*)-7-hydroxy-12-methyl-9-methylene-13-(trimethylsiloxy)-3-oxatetracyclo<5.4.1.1.1,8.04,12>tridecan-2-one