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15-(tert-butyldimethylsiloxy)-12,13-epoxytrichothecane-9-ene

15-(tert-butyldimethylsiloxy)-12,13-epoxytrichothecane-9-ene

CAS号：82891-18-7

英文名：15-(tert-butyldimethylsiloxy)-12,13-epoxytrichothecane-9-ene

分子式

C21H36O4Si

熔点

116 - 118 °C (正己烷)

密度

分子量

380.594

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

15-(tert-butyldimethylsiloxy)-12,13-epoxytrichothecane-9-ene

英文名称

15-(tert-butyldimethylsiloxy)-12,13-epoxytrichothecane-9-ene

中文别名

英文别名

CAS号

82891-18-7

分子式

C21H36O4Si

分子量

380.594

精确质量

380.238

PSA

51.22

LOGP

4.042

物化性质

熔点

116 - 118 °C (正己烷)

合成路线

共找到3条合成路线 >

15-(tert-butyldimethylsiloxy)-4α-tosyloxytrichothecane-9,12-diene

15-(tert-butyldimethylsiloxy)-4α-tosyloxytrichothecane-9,12-diene

15-(tert-butyldimethylsiloxy)-12,13-epoxytrichothecane-9-ene

15-(tert-butyldimethylsiloxy)-12,13-epoxytrichothecane-9-ene

上游原料

共找到13个上游原料 >

(1R*,2'R*,4R*,8R*)-8-methyl-3-oxabicyclo<3.3.0>octa-2,7-dione-1-spiro-1'-(4'-methyl-2'-(trimethylsiloxy)-3'-cyclohexene)

(1R*,2'R*,4R*,8R*)-8-methyl-3-oxabicyclo<3.3.0>octa-2,7-dione-1-spiro-1'-(4'-methyl-2'-(trimethylsiloxy)-3'-cyclohexene)

(1R,2S,7S,9S,11R)-2-Hydroxymethyl-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol

(1R,2S,7S,9S,11R)-2-Hydroxymethyl-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol

rac-(1R,2R,3a'R,6a'R)-5'-bromo-3a',4-dimethyl-2-((trimethylsilyl)oxy)-3a',5',6',6a'-tetrahydro-2'H,4'H-spiro[cyclohexane-1,3'-cyclopenta[b]furan]-3-ene-2',4'-dione

rac-(1R,2R,3a'R,6a'R)-5'-bromo-3a',4-dimethyl-2-((trimethylsilyl)oxy)-3a',5',6',6a'-tetrahydro-2'H,4'H-spiro[cyclohexane-1,3'-cyclopenta[b]furan]-3-ene-2',4'-dione

(1S,2R,7R,9R,11R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol

(1S,2R,7R,9R,11R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol

rac-(3R,3aR,5S,6aS,10aR)-3a,8-dimethyl-4-methylene-3,3a,4,5,6a,9-hexahydro-1H,10H-3,5-methanofuro[3,4-d]chromen-1-one

rac-(3R,3aR,5S,6aS,10aR)-3a,8-dimethyl-4-methylene-3,3a,4,5,6a,9-hexahydro-1H,10H-3,5-methanofuro[3,4-d]chromen-1-one

15-(tert-butyldimethylsiloxy)-4α-hydroxytrichothecane-9,12-diene

15-(tert-butyldimethylsiloxy)-4α-hydroxytrichothecane-9,12-diene

下游产品

共找到3个下游商品 >

(2S,4'R,5'S,5a'S,9a'R)-5a'-(chloromethyl)-5',8'-dimethyl-2',3',4',5',5a',6',7',9a'-octahydrospiro[oxirane-2,10'-[2,5]methanobenzo[b]oxepin]-4'-yl acetate

(2S,4'R,5'S,5a'S,9a'R)-5a'-(chloromethyl)-5',8'-dimethyl-2',3',4',5',5a',6',7',9a'-octahydrospiro[oxirane-2,10'-[2,5]methanobenzo[b]oxepin]-4'-yl acetate

上游原料

(1R*,2'R*,4R*,8R*)-8-methyl-3-oxabicyclo<3.3.0>octa-2,7-dione-1-spiro-1'-(4'-methyl-2'-(trimethylsiloxy)-3'-cyclohexene) (1R,2S,7S,9S,11R)-2-Hydroxymethyl-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol rac-(1R,2R,3a'R,6a'R)-5'-bromo-3a',4-dimethyl-2-((trimethylsilyl)oxy)-3a',5',6',6a'-tetrahydro-2'H,4'H-spiro[cyclohexane-1,3'-cyclopenta[b]furan]-3-ene-2',4'-dione (1S,2R,7R,9R,11R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol rac-(3R,3aR,5S,6aS,10aR)-3a,8-dimethyl-4-methylene-3,3a,4,5,6a,9-hexahydro-1H,10H-3,5-methanofuro[3,4-d]chromen-1-one 15-(tert-butyldimethylsiloxy)-4α-hydroxytrichothecane-9,12-diene 5,14-Dimethyl-2,10-dioxa-9,13-dioxotetracyclo[6.4.2.03,8.011,14]tetradecan-4-ene (1S*,2R*,6R*,7R*,11S*)-6-hydroxy-2-methyl-1-(methoxycarbonyl)-8-methylene-3-oxo-11-(trimethylsiloxy)tricyclo<5.3.1.02,6>undecane 15-(tert-butyldimethylsiloxy)-4α-tosyloxytrichothecane-9,12-diene (1S*,4S*,7R*,8R*,12S*,13S*)-7-hydroxy-12-methyl-9-methylene-13-(trimethylsiloxy)-3-oxatetracyclo<5.4.1.1.1,8.04,12>tridecan-2-one

下游产品

(2S,4'R,5'S,5a'S,9a'R)-5a'-(chloromethyl)-5',8'-dimethyl-2',3',4',5',5a',6',7',9a'-octahydrospiro[oxirane-2,10'-[2,5]methanobenzo[b]oxepin]-4'-yl acetate