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5,14-Dimethyl-2,10-dioxa-9,13-dioxotetracyclo[6.4.2.03,8.011,14]tetradecan-4-ene

CAS号：82916-71-0

英文名：5,14-Dimethyl-2,10-dioxa-9,13-dioxotetracyclo[6.4.2.03,8.011,14]tetradecan-4-ene

分子式

C14H16O4

熔点

148.5 - 150.5 °C (乙醚)

密度

分子量

248.274

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

5,14-Dimethyl-2,10-dioxa-9,13-dioxotetracyclo[6.4.2.03,8.011,14]tetradecan-4-ene

英文名称

5,14-Dimethyl-2,10-dioxa-9,13-dioxotetracyclo[6.4.2.03,8.011,14]tetradecan-4-ene

中文别名

英文别名

CAS号

82916-71-0

分子式

C14H16O4

分子量

248.274

精确质量

248.105

PSA

52.6

LOGP

1.3848

物化性质

熔点

148.5 - 150.5 °C (乙醚)

合成路线

共找到12条合成路线 >

82891-05-2

(1R*,2'R*,4R*,8R*)-8-methyl-3-oxabicyclo<3.3.0>octa-2,7-dione-1-spiro-1'-(4'-methyl-2'-(trimethylsiloxy)-3'-cyclohexene)

82916-71-0

5,14-Dimethyl-2,10-dioxa-9,13-dioxotetracyclo[6.4.2.03,8.011,14]tetradecan-4-ene

上游原料

共找到6个上游原料 >

82891-05-2

(1R*,2'R*,4R*,8R*)-8-methyl-3-oxabicyclo<3.3.0>octa-2,7-dione-1-spiro-1'-(4'-methyl-2'-(trimethylsiloxy)-3'-cyclohexene)

82891-06-3

rac-(1R,2R,3a'R,6a'R)-5'-bromo-3a',4-dimethyl-2-((trimethylsilyl)oxy)-3a',5',6',6a'-tetrahydro-2'H,4'H-spiro[cyclohexane-1,3'-cyclopenta[b]furan]-3-ene-2',4'-dione

73912-36-4

Silane, trimethyl[[(1E)-3-methyl-1,3-butadienyl]oxy]-

82891-03-0

(1S*,2R*,6R*,7R*,11S*)-6-hydroxy-2-methyl-1-(methoxycarbonyl)-8-methylene-3-oxo-11-(trimethylsiloxy)tricyclo<5.3.1.02,6>undecane

82891-04-1

(1S*,4S*,7R*,8R*,12S*,13S*)-7-hydroxy-12-methyl-9-methylene-13-(trimethylsiloxy)-3-oxatetracyclo<5.4.1.1.1,8.04,12>tridecan-2-one

下游产品

共找到12个下游商品 >

82891-10-9

(1R,2S,7S,9S,11R)-2-Hydroxymethyl-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol

82891-15-4

Propionic acid (1S,2R,7R,9R,11R)-2-hydroxymethyl-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-yl ester

82916-70-9

(1R,2S,7R,9S,11R)-2-Hydroxymethyl-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol

87902-56-5

rac-(1aR,3aR,4S,5R,7R,8aS,8bS)-3a-(((tert-butyldimethylsilyl)oxy)methyl)-1a,4-dimethyl-9-methylenedecahydro-4,7-methanooxireno[2',3':5,6]benzo[1,2-b]oxepin-5-ol

82891-17-6

(1S,2R,7R,9R,11R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol

82891-16-5

Propionic acid (2R,7R,11R)-2-(tert-butyl-dimethyl-silanyloxymethyl)-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-yl ester

上游原料

(1R*,2'R*,4R*,8R*)-8-methyl-3-oxabicyclo<3.3.0>octa-2,7-dione-1-spiro-1'-(4'-methyl-2'-(trimethylsiloxy)-3'-cyclohexene) rac-(1R,2R,3a'R,6a'R)-5'-bromo-3a',4-dimethyl-2-((trimethylsilyl)oxy)-3a',5',6',6a'-tetrahydro-2'H,4'H-spiro[cyclohexane-1,3'-cyclopenta[b]furan]-3-ene-2',4'-dione (1S*,2R*,6R*,7R*,11S*)-6-hydroxy-2-methyl-1-(methoxycarbonyl)-8-methylene-3-oxo-11-(trimethylsiloxy)tricyclo<5.3.1.02,6>undecane (1S*,4S*,7R*,8R*,12S*,13S*)-7-hydroxy-12-methyl-9-methylene-13-(trimethylsiloxy)-3-oxatetracyclo<5.4.1.1.1,8.04,12>tridecan-2-one

下游产品

(1R,2S,7S,9S,11R)-2-Hydroxymethyl-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol Propionic acid (1S,2R,7R,9R,11R)-2-hydroxymethyl-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-yl ester (1R,2S,7R,9S,11R)-2-Hydroxymethyl-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol rac-(1aR,3aR,4S,5R,7R,8aS,8bS)-3a-(((tert-butyldimethylsilyl)oxy)methyl)-1a,4-dimethyl-9-methylenedecahydro-4,7-methanooxireno[2',3':5,6]benzo[1,2-b]oxepin-5-ol (1S,2R,7R,9R,11R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-ol Propionic acid (2R,7R,11R)-2-(tert-butyl-dimethyl-silanyloxymethyl)-1,5-dimethyl-12-methylene-8-oxa-tricyclo[7.2.1.02,7]dodec-5-en-11-yl ester 15-(tert-butyldimethylsiloxy)-4α-hydroxytrichothecane-9,12-diene 15-(tert-butyldimethylsiloxy)-12,13-epoxytrichothecane-9-ene 15-(tert-butyldimethylsiloxy)-4α-tosyloxytrichothecane-9,12-diene 15-hydroxy-4-oxo-11-epitrichothecane-9,12-diene hemiketal